2,2,2-TRICHLOROETHYL ACETATE synthesis
- Product Name:2,2,2-TRICHLOROETHYL ACETATE
- CAS Number:625-24-1
- Molecular formula:C4H5Cl3O2
- Molecular Weight:191.44
108-05-4
584 suppliers
$4.00/1000g
115-20-8
309 suppliers
$8.00/25g
625-24-1
15 suppliers
$224.00/5ml-f
Yield: 100%
Reaction Conditions:
with dilithium tetra(tert-butyl)zincate in toluene at 0; for 1 h;Inert atmosphere;
Steps:
General procedure: A typical procedure was as follows. Vinyl acetate (5.0mmol), benzyl alcohol (1.0mmol), and solvent (2.0mL) were added to a glass ampoule which had been degassed and filled with nitrogen. A solution of TBZL (0.1mmol) in THF was added under a nitrogen atmosphere to the ampoule placed in a constant-temperature bath. Then the mixture was kept at 25 or 0°C and stirred. After a prescribed period, the mixture was diluted with CDCl3 and transformed in a NMR tube. Conversion of the reaction was determined by 1H NMR at 400MHz.
References:
Oshimura, Miyuki;Oda, Yuki;Kondoh, Keita;Hirano, Tomohiro;Ute, Koichi [Tetrahedron Letters,2016,vol. 57,# 19,p. 2070 - 2073]
115-20-8
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$8.00/25g
75-36-5
587 suppliers
$17.92/100G
625-24-1
15 suppliers
$224.00/5ml-f
74-85-1
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$79.00/11l
79-20-9
569 suppliers
$14.00/100g
625-24-1
15 suppliers
$224.00/5ml-f
115-20-8
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$8.00/25g
108-24-7
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$14.00/250ML
625-24-1
15 suppliers
$224.00/5ml-f
302-17-0
464 suppliers
$27.00/1mg
625-24-1
15 suppliers
$224.00/5ml-f