ChemicalBook CAS DataBase List 2'-O-(tert-Butyldimethylsilyl)-6,7-dehydropaclitaxel

2'-O-(tert-Butyldimethylsilyl)-6,7-dehydropaclitaxel synthesis

3synthesis methods

Product Name:2'-O-(tert-Butyldimethylsilyl)-6,7-dehydropaclitaxel
CAS Number:165065-02-1
Molecular formula:C53H63NO13Si
Molecular Weight:950.15

33069-62-4 Synthesis

33069-62-4
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2'-O-(tert-Butyldimethylsilyl)-6,7-dehydropaclitaxel

165065-02-1
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Yield:-

Steps:

Multi-step reaction with 2 steps
1: 99 percent / imidazole / dimethylformamide
2: 1.) Tf₂O, 2.) DBU / 1.) pyridine, 25 deg C, 2.) 25 deg C

References:

Wender, Paul A.;Lee, Daesung;Lal, Tapan K.;Horwitz, Susan B.;Rao, Srinivasa [Bioorganic and Medicinal Chemistry Letters,1997,vol. 7,# 14,p. 1941 - 1944]

18162-48-6 Synthesis

18162-48-6
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$9.00/5g

165065-02-1
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References

114655-02-6 Synthesis

114655-02-6
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165065-02-1
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References

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(αR,βS)-β-[[(1,1-DiMethylethoxy)carbonyl]aMino]-α-hydroxy-4-(phenylMethoxy)-benzenepropanoic Acid Ethyl Ester Epothilone B 6-CHLORO-4-CHLOROMETHYL-7-HYDROXY-CHROMEN-2-ONE (4S,5R)-2,2-DiMethyl-4-[4-(phenylMethoxy)phenyl]-N-DiMethylethoxycarbonyl-3,5-oxazolidinecarboxylic Acid Ethyl Ester Methyl (2R,3S)-3-(benzoylamino)-2-hydroxy-3-phenylpropanoate (4S,5R)-2,2-DiMethyl-4-[4-(phenylMethoxy)phenyl]-3,5-oxazolidinedicarboxylic Acid 3-(1,1-DiMethylethyl) Ester 2-Bromobenzene-1,3-dialdehyde 4-[(1E,3S,5Z,8R/S,10S)-3,11-Bis-{[tert-butyl(dimethyl)silyl]oxy}-2,6,10-trimethyl-8-(phenylsulfonyl)undeca-1,5-dienyl]-2-methyl-1,3-thiazole (3S,6R,7S,12Z,15S,16E)-3,7-Bis-{[tert-butyl(dimethyl)silyl]oxy}-15-hydroxy-4,4,6,8,12,16-hexamethyl-17-(2-methyl-1,3-thiazol-4-yl)-5-oxoheptadeca-12,16-dienoic Acid 13-{[(3-t-Boc)-2,2-dimethyl-4S-phenyl-1,3-oxazolidin-5R-yl]formyl}-7-O-(2,2,2-trichloroethyl)oxy]carbonyl) Baccatin III

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2'-O-(tert-Butyldimethylsilyl)-6,7-dehydropaclitaxel synthesis

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