(1S, 2R)-2-(Benzyloxymethyl)-1-hydroxy-3-cyclopentene synthesis
- Product Name:(1S, 2R)-2-(Benzyloxymethyl)-1-hydroxy-3-cyclopentene
- CAS Number:110567-21-0
- Molecular formula:C13H16O2
- Molecular Weight:204.26
3587-60-8
323 suppliers
$10.00/1g
4984-82-1
122 suppliers
$86.90/0.1mole
110567-21-0
185 suppliers
$7.00/1g
Yield:110567-21-0 73%
Reaction Conditions:
Stage #1: Benzyloxymethyl chloride;sodium cyclopentadienylide in tetrahydrofuran;N,N-dimethyl-formamide at -40; for 0.25 h;
Stage #2: with L-diisopinocampheylborane in tetrahydrofuran at -10; for 48 h;
Stage #3: with sodium hydroxide;dihydrogen peroxide at 20; for 12 h;Further stages.;
References:
Woll, Matthew G.;Fisk, John D.;LePlae, Paul R.;Gellman, Samuel H. [Journal of the American Chemical Society,2002,vol. 124,# 42,p. 12447 - 12452]
![Benzene, [(2,4-cyclopentadien-1-ylmethoxy)methyl]-](/CAS/20200119/GIF/39939-07-6.gif)
39939-07-6
2 suppliers
inquiry
110567-21-0
185 suppliers
$7.00/1g
3587-60-8
323 suppliers
$10.00/1g
110567-21-0
185 suppliers
$7.00/1g
![(1S,2R,3S,5R)-2-(Benzyloxymethyl)-6-oxabicyclo[3.1.0]hexan-3-ol](/CAS/GIF/117641-39-1.gif)
117641-39-1
91 suppliers
inquiry
110567-21-0
185 suppliers
$7.00/1g