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Chemical Communications

Chemical Communications

IF: 4.29
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Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst?

Published:26 July 2017 DOI: 10.1039/C7CC04776B PMID: 28762402
Yuki Ando, Takuto Kamatsuka, Hiroshi Shinokubo and Yoshihiro Miyake

Abstract

Visible light-mediated α-arylation of α,β-unsaturated imides is achieved via aminium radicals generated from diarylalkylamines using a photoredox catalyst. On the basis of emission quenching experiments, a plausible pathway of the reaction is discussed.

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