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??????????? ??? ???
?? ??:
756-79-6
???:
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???(??):
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???:
Dimethyl methylphosphonate
???(??):
DMMP;Fyrol dmmp;DIMETHYL METHANEPHOSPHONATE;Metaran;pyroldmmp;NSC 62240;fyroldmmp;NCI-C54762;Pyrol DMMP;Reoflam DMMP
CBNumber:
CB8418753
???:
C3H9O3P
??? ??:
124.08
MOL ??:
756-79-6.mol
MSDS ??:
SDS

??????????? ??

???
<50°
?? ?
181 °C(lit.)
??
1.145 g/mL at 25 °C(lit.)
???
<0.1 mm Hg ( 20 °C)
???
n20/D 1.413(lit.)
???
156 °F
???
?????, ???(?? ??) ? ???
?? ?? (pKa)
pKa (20°) in water: 2.37
??? ??
??
Specific Gravity
1.16
??
???
???
21 ºC?? >=10g/100mL
Merck
14,3391
BRN
878263
???
???. ?? ???, ?? ??? ???? ????. ?? ??? ????? ????? ? ????. ?? ???? ??? ???????.
LogP
-0.61
????
2.37 at 20℃
CAS ??????
756-79-6(CAS DataBase Reference)
NIST
Phosphonic acid, methyl-, dimethyl ester(756-79-6)
EPA
Dimethyl methylphosphonate (756-79-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,Xi
?? ???? ?? 46-36-62
????? 53-26-45
????(UN No.) 2810
WGK ?? 2
RTECS ?? SZ9120000
?? ?? ?? Irritant/Toxic
TSCA Yes
?? ?? ??? 756-79-6(Hazardous Substances Data)
?? LD50 in rats, mice (mg/kg): 10190, >6810 orally (Rowland)
???? ?? KE-11543
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H340 ???? ??? ??? ? ?? (????? ???? ????? ???? ???? ???? ??? ?? ????? ??? ???? ??) ???? ???? ?? ?? 1A, 1B ?? GHS hazard pictograms
??????:
P201 ?? ? ?? ???? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
2
3 0

??????????? MSDS


DMMP

??????????? C??? ??, ??, ??

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colourless liquid

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Dimethyl methylphosphonate is used as a catalyst and a reagent in organic synthesis for the conversion of esters to ketophosphonates. It is an additive for the synthesis of unsaturated polyester resin which has flame retardant high phosphorous and UV-cured epoxy acrylate. It finds application as hydraulic fluids as well.

?? ??

Clear colorless liquid with a pleasant odor.

??? ?? ??

Highly flammable. Water soluble. Hydrolyzes slowly upon contact with water.

?? ???

Dimethyl methylphosphonate is incompatible with strong oxidizing agents and strong bases. Dimethyl methylphosphonate reacts with organic halides at 302-392° F. When heated to temperatures greater than 302° F, Dimethyl methylphosphonate will act as an alkylating agent with basic nitrogen compounds and phenols. Dimethyl methylphosphonate reacts with enol lactones. Dimethyl methylphosphonate has plasticizing properties and may soften or deteriorate some plastics and elastomers (particularly vinyl-based resins, neoprene and natural rubbers) upon contact.

????

Dimethyl methylphosphonate (DMMP) administered to male rats is a reproductive toxicant and carcinogen. Effects in humans are unknown.

????

Dimethyl methylphosphonate is combustible.

Safety Profile

Moderately toxic by intravenous route. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. An experimental nerve gas stimulant. A flame retardant. When heated to decomposition it emits toxic fumes of POx

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