アルミニウムイソプロポキシド 化學(xué)特性,用途語,生産方法
外観
白色, 結(jié)晶~粉末又は塊
溶解性
水で分解, ヘキサン, ベンゼン, トリクレン、エタノール, イソプロパノールに可溶。(アルコールにはあまり溶けない)エタノールに溶けやすく、水で分解する。
解説
アルミニウムトリイソプロポキシド,白色の固體.融點(diǎn)118 ℃,沸點(diǎn)145~150 ℃(670 Pa).潮解性がある.エタノール,ベンゼンに可溶.アルデヒドの不均化(ティチェンコ反応)や,アルデヒド,ケトンの酸化,還元反応(メアワイン-ポンドルフ-バーレー還元,オッペナウアー酸化)の觸媒として使用される.そのほか,脫水剤,塗料,布地の防水加工剤などに用いられる.
森北出版「化學(xué)辭典(第2版)
用途
有機(jī)合成において反応試剤、觸媒として用いられる。この化合物の実際の構(gòu)造は複雑で、さらに結(jié)晶化後の時(shí)間や、溶媒による変化があることが知られている。
製造
アルミニウムトリイソプロポキシド,塩化水銀(Ⅱ)の存在下でアルミニウムと2-プロパノールから合成される.イソプロポキシド架橋した三量體と四量體が知られているが,通常は四量體として存在する.
説明
Aluminium isopropoxide is usually described with the formula Al(O-i-Pr)3, where i-Pr is the isopropyl group (CH(CH3)2). This colourless solid is a useful reagent in organic synthesis. The structure of this compound is complex, possibly time dependent, and may depend on the solvent. It is primarily used in the oil and gas industry in combination with phosphate esters to form an anionic association polymer in which the aluminium as the cross-linking agent. Such gelling agents are used as fluid loss control additives in drilling operations.
化學(xué)的特性
Aluminum isopropoxide on the market is mostly white translucent block, cylindrical small block solid or powder, soluble in isopropanol, ethanol, toluene, benzene, carbon tetrachloride, chloroform and other organic solvents (easy to dissolve when heated to 70 °C), decomposed when it meets water, has strong water absorption, and is easily decomposed into aluminum hydroxide and isopropanol.)
使用
Alkyl phosphate esters in conjunction with aluminium isopropoxide have been used as fluid loss additives in drilling fluid compositions. It is important for drilling fluids to efficiently and quickly form a filter cake to minimise fluid loss and allow flow of fluids into the wellbore during production. In the alkyl phosphate ester case, it is cross‐linked with the aluminium compound to form a complex anionic polymer, which acts as a gelling agent to prevent fluid loss.
製造方法
Aluminum isopropoxide is synthesized by the reaction of isopropanol and aluminum under the catalysis of alumina. Raw material consumption quota: isopropyl alcohol 1255kg/t, aluminum 166kg/t.
火災(zāi)危険
The flash point of this compound is 26°C
(79°F) (Bretzinger and Josten). It is less
flammable than the sec- and tert-alkoxides
of alkali metals. Ignition may occur when
this compound is heated in moist air.It decomposes in water. The reaction is exothermic,
producing isopropanol. It may decompose
when heated to 250°C (482°F), producing
highly flammable isopropyl ether.
純化方法
Redistil it under vacuum. Hygroscopic. [Robinson & Peak J Phys Chem 39 1127 1935, Beilstein 1 IV 1468.]
アルミニウムイソプロポキシド 上流と下流の製品情報(bào)
原材料
準(zhǔn)備製品