| Identification | Back Directory | [Name]
Benzenesulfonylazide | [CAS]
938-10-3 | [Synonyms]
Benzenesulfonylazide
(Phenylsulfonyl) azide
N-diazobenzenesulfonamide
Benzenesulfonic acid azide | [Molecular Formula]
C6H5N3O2S | [MDL Number]
MFCD11632117 | [MOL File]
938-10-3.mol | [Molecular Weight]
183.188 |
| Hazard Information | Back Directory | [Synthesis Reference(s)]
Tetrahedron Letters, 25, p. 4651, 1984 DOI: 10.1016/S0040-4039(01)91224-9 | [Synthesis]
Benzenesulfonylazide is prepared by the reaction of Benzenesulfonyl Chloride with excess Sodium Azide in a water-ethanol mixture. The formation of ethyl benzenesulfonate as a byproduct may be avoided by addition of neat benzenesulfonyl chloride to an ethanolic solution of sodium azide. A preparation of benzenesulfonyl azide by oxidation of phenylsulfonylhydrazine in the presence of clay-supported iron(III) nitrate (clayfen) has been reported. | [storage]
Crude benzenesulfonyl azide when heated detonates violently. Use in a fume hood. | [Purification Methods]
recrystallization from ethanol. |
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