Identification | Back Directory | [Name]
1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl- | [CAS]
83622-41-7 | [Synonyms]
Dichloromethyl pinacolboronate Pinacol (dichloromethyl) boronate Pinacol (dichloromethyl) boronate >=95% (Dichloromethyl)boronic Acid Pinacol Ester 2-(dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1,3,2-Dioxaborolane, 2-(dichloroMethyl)-4,4,5,5-tetraMethyl- 2-(Dichloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(WS203860) | [Molecular Formula]
C7H13BCl2O2 | [MDL Number]
MFCD27976342 | [MOL File]
83622-41-7.mol | [Molecular Weight]
210.89 |
Hazard Information | Back Directory | [Uses]
Pinacol (dichloromethyl) boronate is a general reagent that was employed by Prof. Greg C. Fu and coworkers to achieve the iterative synthesis of asymmetric (secondary) alkyl boronate esters. These can be further derivatized through a growing suite of chemical transformations developed in the last decade (cross coupling, oxidation, amination, halogenation) that proceed with stereochemical fidelity. |
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