Identification | Back Directory | [Name]
1-(BROMOACETYL)PYRENE | [CAS]
80480-15-5 | [Synonyms]
1-(BROMOACETYL)PYRENE 1-(Bromoacetyl)pyrene 97% 2-bromo-1-(1-pyrenyl)Ethanone 2-bromo-1-(pyren-3-yl)ethanone 2-broMo-1-(pyren-1-yl)ethanone Ethanone, 2-bromo-1-(1-pyrenyl)- 2-bromo-1-(pyren-1-yl)ethan-1-one | [Molecular Formula]
C18H11BrO | [MDL Number]
MFCD00191839 | [MOL File]
80480-15-5.mol | [Molecular Weight]
323.18 |
Chemical Properties | Back Directory | [Melting point ]
129-131 °C (lit.) | [Boiling point ]
476.7±18.0 °C(Predicted) | [density ]
1.563±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,2-8°C | [form ]
Solid | [color ]
Yellow to Dark Yellow |
Hazard Information | Back Directory | [Chemical Properties]
Yellow solid | [Uses]
1-(Bromoacetyl)pyrene is suitable for use in the following studies:
- As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
- As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
- As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.
It may also be used in the following studies:
- As a photoremovable protecting group for carboxylic acids and amino acids.
- As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
- As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
- As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.
| [General Description]
1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes. |
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