| Identification | Back Directory | [Name]
Lithium diisobutyl-tert-butoxyaluminum hydride | [CAS]
77299-63-9 | [Synonyms]
LDBBA
-tert-butoxyaL
ithium diisobutyL
Lithium diisobutyl-tert-butoxyaluminum hydride
Lithium diisobutyl-tert-butoxyaluminum hydride solution
Lithium diisobutyl-tert-butoxyaluminum hydride solution 0.25M in THF/hexanes
Lithium diisobutyl-tert-butoxyaluminum hydride 0.25 M in THF/hexanes solution
LithiuM diisobutyl-tert-butoxyaluMinuM hydride, 0.25 M solution in THF/hexanes | [Molecular Formula]
C12H28AlLiO | [MDL Number]
MFCD16621454 | [MOL File]
77299-63-9.mol | [Molecular Weight]
222.273 |
| Chemical Properties | Back Directory | [density ]
0.795 g/mL at 25 °C | [storage temp. ]
2-8°C | [form ]
liquid | [InChI]
InChI=1S/C4H9O.2C4H8.Al.Li.H/c1-4(2,3)5;2*1-4(2)3;;;/h1-3H3;2*1,4H,2-3H3;;;/q3*-1;+2;+1; | [InChIKey]
AHOWROKZHSVLIH-UHFFFAOYSA-N | [SMILES]
[O-](C(C)(C)C)[Al+3]([H-])([CH-]C(C)C)[CH-]C(C)C.[Li+] |
| Hazard Information | Back Directory | [Uses]
Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of:
- Aromatic and aliphatic nitriles to aldehydes.
- Aromatic and aliphatic esters to aldehydes.
- Tertiary amides to aldehydes.
| [reaction suitability]
reagent type: reductant |
|
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