Identification | Back Directory | [Name]
(R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL | [CAS]
65355-14-8 | [Synonyms]
6,6' 7,7' 8,8' 8,8′ 7,7′ (R)-(+)-2 (R)-(+)-5,5' (R)-(+)-5,5′ Octahydro-(R)-BINOL -Octahydro-1,1' -Octahydro-1,1′ -bi-2-naphthol (R)-(+)-5,5' (R)-5,5,6,6,7,7,8,8-OCTAHYDRO(1,1-BI-NAP (R)-5,5'-6,6'-7,7'-8,8'-OCTAHYDRO-BI-2-& 5,5',6,6',7,7',8,8'-Octahydro-bi-2-naphthol 5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-BI-2-NAPHTHOL (R)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL (R)-(+)-5,5,6,67,7,8,8-Octahydro-1,1-bi-2-naphtol,99% (R)-(+)-5,5μ,6,6μ,7,7μ,8,8μ-Octahydro-1,1μ-2-naphthol (+/-)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL (R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol,98% (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL (R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2,2'-naphthol (R)-(+)-5,5'',6,6''7,7'',8,8''-OCTAHYDRO-1,1''-BI-2-NAPHTOL (R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol,99% (R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol, 98%e.e. (R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol (1R)-5,5',6,6',7,7',8,8'-octahydro[1,,1'-binaphthalene]-2,2'-diol (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO(1,1'BINAPHTHALENE)-2,2'-DIOL (S)-(-)-5,5',6,6',7,7',8,8'-OCTAHYDRO(1,1'BINAPHTHALENE)-2,2'-DIOL (S)-(-)-2,2'-DIHYDROXY-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL (R)-(+)-2,2'-DIHYDROXY-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL (R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2,2'-naphthol, ee: 99% | [Molecular Formula]
C20H22O2 | [MDL Number]
MFCD02093485 | [MOL File]
65355-14-8.mol | [Molecular Weight]
294.39 |
Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
165-169 °C(lit.)
| [alpha ]
+48° to 53° (c 1.1, CHCl3) | [Boiling point ]
516.7±50.0 °C(Predicted) | [density ]
1.200 | [refractive index ]
50 ° (C=1, CHCl3) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
almost transparency in Chloroform | [form ]
Powder | [pka]
9.62±0.20(Predicted) | [color ]
off-white | [optical activity]
[α]20/D +73°, c = 1 in THF | [Sensitive ]
Hygroscopic | [CAS DataBase Reference]
65355-14-8 |
Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-2-naphthol can be used:
- As a starting material for the preparation of octahydro-binaphthyl based organic light-emitting diodes.
- As a ligand in the 1,4-hydrophosphinylation of methyl cyclohexene-1-carboxylate using diphenylphosphine oxide, applicable in the synthesis of CyPHOX ligands.
|
Spectrum Detail | Back Directory | [Spectrum Detail]
(R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL(65355-14-8)MS (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL(65355-14-8)1HNMR (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL(65355-14-8)13CNMR (R)-(+)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BI-2-NAPHTHOL(65355-14-8)IR
|
|
|