| Identification | Back Directory | [Name]
BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX | [CAS]
63348-81-2 | [Synonyms]
Chloroborane methyl
MONOCHLOROBORANE-METHYLSULFIDE
Monochloroborane-dimethyl sulfide
CHLOROBORANE-METHYL SULFIDE COMPLEX
Chloro(dimethyl sulfide)dihydroboron
Chloroborane-methyl sulfide 1:1 complex
Monochloroborane-dimethyl sulfide (1:1)
MONOCHLOROBORANE-METHYL SULFIDE COMPLEX
Monochloroborane-dimethylsulfide complex
BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
Boron, chlorodihydrothiobismethane-, (T-4)-
Boron monochloride methyl sulfide complex, monoChloroborane methyl sulfide complex
Chloroborane methyl sulfide complex,Boron monochloride methyl sulfide complex, monoChloroborane methyl sulfide complex | [Molecular Formula]
C2H9BClS | [MDL Number]
MFCD00013210 | [MOL File]
63348-81-2.mol | [Molecular Weight]
111.41 |
| Chemical Properties | Back Directory | [density ]
1.059 g/mL at 25 °C (lit.) | [Fp ]
76 °F | [solubility ]
soluble in Benzene, Chloroform | [form ]
Oil | [color ]
Clear Colourless | [Stability:]
Hygroscopic, Moisture Sensitive |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Substitution reactions
- Boronation reactions
- Preparation of diborylamines
- Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions
- Asymmetrical aldol reactions with a-chiral aldehydes
- Addition reaction with α-pinene
| [Preparation]
Monochloroborane-dimethyl sulfide is prepared by redistribution of Borane-Dimethyl Sulfide (BMS) and Boron Trichloride. SMe2 and by the reaction of BMS with CCl4. The reagent is in equilibrium with approximately 15% each of BHCl2.SMe2 and BMS.
| [reaction suitability]
reagent type: reductant | [Precautions]
corrosive liquid; flammable; stench; reacts violently with water. Handle and store under nitrogen or argon. Stable indefinitely when stored under nitrogen at 25 °C. Use in a fume hood.
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Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
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| Website: |
http://www.energy-chemical.com |
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