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ChemicalBook--->CAS DataBase List--->53317-87-6

53317-87-6

53317-87-6 Structure

53317-87-6 Structure
IdentificationBack Directory
[Name]

TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE
[CAS]

53317-87-6
[Synonyms]

TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TET&
Oxotris((triphenylphosphine)gold) tetrafluoroborate
Oxotris(triphenylphosphine)trigold tetrafluoroborate
TRIS(TRIPHENYLPHOSPHINEGOLD)OXOIUM TETRAFLUOROBORATE
TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE
Tris(triphenylphosphineaurio)oxonium tetrafluoroborate
TRIS[TRIPHENYLPHOSPHINEGOLD (I)]OXONIUM TETRAFLUOROBORATE
Tris[triphenylphosphinegold(I)]oxoniumtetrafluoroborate,98%
Tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate
[Molecular Formula]

C54H45Au3BF4OP3
[MDL Number]

MFCD06658141
[MOL File]

53317-87-6.mol
[Molecular Weight]

1480.56
Chemical PropertiesBack Directory
[Melting point ]

207°C (dec.)
[form ]

Powder
[color ]

off-white
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for the Claisen Rearrangement of propargyl vinyl ethers. Chirality is efficiently transferred.
  2. Catalyst for the oxidative cleavage of a Carbon-Carbon triple bond in (Z)-Enynols and cyclization.
Reactions of 53317-87-6
Hazard InformationBack Directory
[Uses]

Used in a variety of gold catalyzed reactions including propargyl Claisen rearrangements.
[reaction suitability]

core: gold
reagent type: catalyst
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