| Identification | Back Directory | [Name]
MERCURY(II) TRIFLUOROMETHANESULFONATE | [CAS]
49540-00-3 | [Synonyms]
Hg(OTf)2
MERCURY TRIFLATE
mercuric triflate
mercury(ii) triflate
Mercury(II) Triflate (2:1)
Mercury trifluoromethanesulfonate
Mercury(Ⅱ) trifluoroMethanesulfonate
MERCURY(II) TRIFLUOROMETHANESULFONATE
MERCURY(II) TRIFLUOROMETHANESULPHONATE
Mercury(II)trifluoromethanesulfonate,98%
MERCURY(II) TRIFLUOROMETHANESULFONATE 98%
MercurytrifluoromethanesulfonateMercurytriflatepowder
Mercury(II) trifluoromethanesulfonate, 99.9% metals basis
MERCURY(II) TRIFLUOROMETHANESULFONATE (MERCURY TRIFLATE)
Methanesulfonic acid,1,1,1-trifluoro-, mercury(2+) salt (2:1)
MERCURY (II) TRIFLUOROMETHANESULFONATE 98% (MERCURY TRIFLATE) | [Molecular Formula]
C2F6HgO6S2 | [MDL Number]
MFCD00144746 | [MOL File]
49540-00-3.mol | [Molecular Weight]
498.73 |
| Chemical Properties | Back Directory | [Melting point ]
>350 °C(lit.)
| [solubility ]
It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene. | [form ]
Powder | [color ]
White | [Sensitive ]
Moisture Sensitive | [Exposure limits]
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3 | [Stability:]
hygroscopic |
| Hazard Information | Back Directory | [Uses]
Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions. | [reaction suitability]
core: mercury
reagent type: catalyst |
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