Identification | Back Directory | [Name]
6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL | [CAS]
35836-73-8 | [Synonyms]
(-)-NOPOL 2-((1R,5S) (1R)-(-)-NOPOL (1R)-(-)-Nopol,98% (1R)-(-)-Nopol 98% Dimethylbicyclohepteneethanol 6,6-DIMETHYL-2-NORPINENE-2-ETHANOL -6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl) 6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL 6,6Dimethyllbicyclo(3.1.1)hept-2-ene-2-ethanol (-)-[(1R)-6,6-Dimethylnorpinane-2-ene]-2-ethanol (1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol (1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL (1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol (1α,5α)-7,7-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol (1β,5β)-6,6-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)- (1β,5β)-2-(2-Hydroxyethyl)-6,6-dimethylbicyclo[3.1.1]hepta-2-ene (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol (-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol | [EINECS(EC#)]
252-744-2 | [Molecular Formula]
C11H18O | [MDL Number]
MFCD00075187 | [MOL File]
35836-73-8.mol | [Molecular Weight]
166.26 |
Chemical Properties | Back Directory | [Appearance]
Clear colorless to light yellow liquid | [Boiling point ]
235-236 °C(lit.)
| [density ]
0.973 g/mL at 25 °C(lit.)
| [vapor pressure ]
2.17Pa at 20℃ | [refractive index ]
n20/D 1.493
| [Fp ]
210 °F
| [storage temp. ]
Refrigerator, under inert atmosphere | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oil | [pka]
15.03±0.10(Predicted) | [color ]
Clear Colourless | [optical activity]
[α]24/D 37°, neat | [Water Solubility ]
333.5mg/L at 20℃ | [Merck ]
14,6683 | [BRN ]
3196379 | [LogP]
3.09 at 30℃ |
Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to light yellow liquid | [Uses]
(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol. | [Application]
(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization. | [Definition]
ChEBI: (-)-Nopol is a monoterpenoid. | [General Description]
(1R)-(-)-Nopol is a chiral terpenol derivative. |
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