| Identification | Back Directory | [Name]
6-CYANOHEXYLZINC BROMIDE | [CAS]
312624-28-5 | [Synonyms]
6-CYANOHEXYLZINC BROMIDE
6-cyanohexylzinc bromide solution
6-Cyanohexylzinc bromide solution 0.5 in THF
6-Cyanohexylzinc bromide solution 0.5M in THF
6-Cyanohexylzinc bromide 0.5 M in Tetrahydrofuran
6-CYANOHEXYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN
6-Cyanohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
6-Cyanohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C7H12BrNZn | [MDL Number]
MFCD01316997 | [MOL File]
312624-28-5.mol | [Molecular Weight]
255.47 |
| Chemical Properties | Back Directory | [density ]
0.944 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
2-8°C | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Hazard Information | Back Directory | [Uses]
6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to synthesize:
- Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
- Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.
|
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
SIGMA-RBI
|
| Tel: |
800 736 3690 (Orders) |
| Website: |
www.sigma-aldrich.com |
|