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ChemicalBook--->CAS DataBase List--->250611-13-3

250611-13-3

250611-13-3 Structure

250611-13-3 Structure
IdentificationBack Directory
[Name]

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
[CAS]

250611-13-3
[Synonyms]

(R,R)Salen AI
Cyclohexanediaminobisdibutylsalicyliden
(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINIUM(III) CHLORIDE
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]aluminum(III)chloride
(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
(1R,2R)-(-)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluMinuM(III) chloride,98% (R,R)-Salen-Al
[Molecular Formula]

C36H52AlClN2O2
[MDL Number]

MFCD02684547
[MOL File]

250611-13-3.mol
[Molecular Weight]

607.24
Chemical PropertiesBack Directory
[Melting point ]

250-255 °C(lit.)
[form ]

Powder
[color ]

yellow
[CAS DataBase Reference]

250611-13-3
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302+H312+H332
[Precautionary statements ]

P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

26-36
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
  2. Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
  3. Catalyst used for the asymmetric hydrocyanation of nitroolefins.
  4. Catalyst used in the reaction of epoxides with heterocumulenes.
Reactions of 250611-13-3_1
Reactions of 250611-13-3_2
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Asymmetric iodolactonizations
  • Cyanosilylation reactions
  • Phospho-aldol catalysis
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