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ChemicalBook--->CAS DataBase List--->2151915-22-7

2151915-22-7

2151915-22-7 Structure

2151915-22-7 Structure
IdentificationBack Directory
[Name]

Methanesulfonato[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[CAS]

2151915-22-7
[Synonyms]

Methanesulfonato(2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl...
Methanesulfonato[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
[Molecular Formula]

C57H45NO3P2PdS
[MOL File]

2151915-22-7.mol
[Molecular Weight]

992.42
Chemical PropertiesBack Directory
[Melting point ]

175-180 °C
[form ]

solid
[InChIKey]

UMZSSCWQSUDMCN-UHFFFAOYSA-N
[SMILES]

P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC2C=CC=CC=2C=1C1C2C=CC=CC=2C=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
[CAS DataBase Reference]

2151915-22-7
Hazard InformationBack Directory
[Uses]

Pd precatalyst for cross-coupling
[General Description]

rac-BINAP-Pd-G3 is a third generation (G3) Buchwald precatalyst. t is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. rac-BINAP-Pd-G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio. It
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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