| Identification | Back Directory | [Name]
1,3,5,7-Tetramethyl-8-(2-di-o-tolylphosphinophenyl)-2,4,6-trioxa-8-phosphaadamantane PAd-DalPhos | [CAS]
1902911-38-9 | [Synonyms]
1,3,5,7-TETRAMETHYL-8-(2-DI-O-TOLYLPHOSPHINOPHENYL)-2,4,6-TRIOXA-8-PHOSPHAADAMANTANEPAD-DALPHOS
2,4,6-Trioxa-8-phosphatricyclo[3.3.1.13,7]decane, 8-[2-[bis(2-methylphenyl)phosphino]phenyl]-1,3,5,7-tetramethyl- | [Molecular Formula]
C30H34O3P2 | [MDL Number]
MFCD31381910 | [MOL File]
1902911-38-9.mol | [Molecular Weight]
504.54 |
| Hazard Information | Back Directory | [Uses]
PAd-DalPhos is a versatile air stable pre-catalyst for C(sp2)-N coupling. It catalyzes N-arylation of amides with (hetero)aryl (pseudo)halide. It can also be used in the synthesis of unsymmetrical 1,3-di(hetero)aryl-1H-indazoles from hydrazine, o-chloro (hetero)benzophenones and (hetero)aryl bromides. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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