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ChemicalBook--->CAS DataBase List--->169689-05-8

169689-05-8

169689-05-8 Structure

169689-05-8 Structure
IdentificationBack Directory
[Name]

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
[CAS]

169689-05-8
[Synonyms]

Rostligand
(S,S)-DACH-phenyl ligand
(1S,2S)-(-)-1,2-TROST LIGAND
1S,2S- DHAC-Phenyl Trost Ligand
(S,S)-DACH-phenyl Trost ligand
95% (S,S)-DACH-Phenyl Trost Ligand
(S,S)-DACH-phenyl Trost ligand 95%
(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.
1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)
BenzaMide,N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]
(1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl)
(1S,2S)-(¨C)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl)
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N''-BIS(2''-DIPHENYLPHOSPHINOBENZOYL) TROST LIGAND
(S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(S,S)-DACH-PhenylTrostLigand
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
[Molecular Formula]

C44H40N2O2P2
[MDL Number]

MFCD01631274
[MOL File]

169689-05-8.mol
[Molecular Weight]

690.75
Chemical PropertiesBack Directory
[Melting point ]

134-136°C
[alpha ]

-134o (C=1 IN METHANOL)
[Boiling point ]

817.0±65.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[pka]

13.35±0.40(Predicted)
[color ]

white to off-white
[optical activity]

[α]20/D -134°, c = 1 in methanol
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 169689-05-8_1
Reactions of 169689-05-8_2
Hazard InformationBack Directory
[Uses]

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