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ChemicalBook--->CAS DataBase List--->1607469-49-7

1607469-49-7

1607469-49-7 Structure

1607469-49-7 Structure
IdentificationBack Directory
[Name]

Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)
[CAS]

1607469-49-7
[Synonyms]

Ir(dmppy)2(dtbbpy)PF6
4,4'-Bis(t-butyl-2,2'-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, 95%
Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-methyl-2-(4-methyl-2-pyridinyl-κN)phenyl-κC]-,(OC-6-33)-, hexafluorophosphate(1-)(1:1)
[Molecular Formula]

C44H48F6IrN4P
[MOL File]

1607469-49-7.mol
[Molecular Weight]

970.08
Chemical PropertiesBack Directory
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[TSCA ]

No
Questions And AnswerBack Directory
[Reaction]

Catalyst used for the direct β-alkylation of aldehydes via photoredox organocatalysis. Reactions of 1607469-49-7
Hazard InformationBack Directory
[Uses]

(Ir[Me(Me)ppy]2(dtbpy))PF6 or Ir(dmppy)2(dtbbpy)PF6 is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.
[reaction suitability]

core: iridium
reagent type: catalyst
reaction type: Photocatalysis
Spectrum DetailBack Directory
[Spectrum Detail]

Ir(dmppy)2(dtbbpy)PF6 or (Ir[Me(Me)ppy]2(dtbpy))PF6(1607469-49-7)1HNMR
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