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ChemicalBook--->CAS DataBase List--->119707-74-3

119707-74-3

119707-74-3 Structure

119707-74-3 Structure
IdentificationBack Directory
[Name]

(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
[CAS]

119707-74-3
[Synonyms]

Dibromonaphtol
(S)-Dibromo-BINOL
(S)-3,3'-Dibromo-BINOL
(S)-Dibromo-bi-2-naphthol
(S)-Dibromo-1,1-Binaphthol
3,3-DIBROMO-1,1'-BI-2-NAPHTHOL
3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-Dibromo-1,1′-Bi-2,2′-naphthol
(R)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(-)-3,3-Dibromo-1,1-bi-2-naphtol
(R)-(+)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-Dibromo-1,1′-Binaphthalene-2,2′-diol
(S)-(-)-3,3'-Dibromo-1,1'-bi-2,2'-naphthol
(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol 96%
(S)-(-)-3,3'-Dibromo-1,1'-Bi-2-Naphthol,98%
(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol,99%
(S)-3,3'-Dibromo-1,1'-bi-2-naphthol, 99%e.e.
(S)-3,3'-Dibromo-1,1'-binaphthalene-2,2'-diol
(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL, 97+%
(S)-(-)-3,3'-DibroMo-1,1'-bi-2-naphthol,Min.98%
(S)-3,3'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
(R)-3,3'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol, min. 98%
[1,1'-Binaphthalene]-2,2'-diol,3,3'-dibroMo-, (1S)-
[Molecular Formula]

C20H12Br2O2
[MDL Number]

MFCD03093629
[MOL File]

119707-74-3.mol
[Molecular Weight]

444.12
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

256-260 °C
[alpha ]

-40° (c 0.15, CHCl3)
[Boiling point ]

469.9±40.0 °C(Predicted)
[density ]

1.761±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

within almost transparency in Methanol
[form ]

Powder
[pka]

6.43±0.50(Predicted)
[color ]

White to brown
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[General Description]

(S)-(-)-3,3′-Dibromo-1,1′-bi-2-naphthol may be used as a catalyst in the preparation of (R)-1-(2-propenyl)-2-(3-phenoxymethoxypropyl)-2-cyclohexenol.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

36/37/38-22
[Safety Statements ]

26-36/37/39-37/39
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

3
[HS Code ]

29081990
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker reactions.
  2. Ligand used in the zinc-catalyzed enantioselective Hetero Diels-Alder reaction.
  3. Catalyst used in syn-selective diastereoselective Petasis reactions.
  4. Catalyst used in asymmetric propargylation of ketones. 
Reactions of 119707-74-3
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