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ChemicalBook--->CAS DataBase List--->11096-82-5

11096-82-5

11096-82-5 Structure

11096-82-5 Structure
IdentificationBack Directory
[Name]

AROCLOR 1260, 1X1ML, ISO, 1000UG/ML
[CAS]

11096-82-5
[Synonyms]

CLORPHENA60
Arclor 1260
phenoclordp6
Aroclor 1260
kanechlor600.
IRIDIUM STAND
PCB Aroclor 1260
aroclor1260(pcb)
chlorodiphenyl(60%cl)
aroclor 1260 solution
Aroclor 1260 (PCB 1260)
[40cfr136(1986)]pcb-1260
Arochlor 1260 in isooctane
Aroclor 1260 in Cyclohexane
Aroclor1260Solution,2mg/L,1ml
Aroclor 1260 @35 μg/mL in MeOH
Aroclor1260Solution,10mg/L,1ml
Aroclor1260Solution,1mg/L,25ml
Aroclor1260Solution,1mg/L,4x1ml
Aroclor1260Solution,200mg/L,1ml
Aroclor 1260 @100 μg/mL in MeOH
Aroclor 1260 @5.0 mg/mL in MeOH
Aroclor1260Solution,100mg/L,1ml
Aroclor1260Solution,100mg/L,5ml
Aroclor1260Solution,1000mg/L,5ml
Aroclor1260Solution,0.10mg/L,2ml
Aroclor1260Solution,0.5mg/L,25ml
AROCLOR 1260, 1X1ML, ISO, 1UG/ML
Arochlor 1260 Solution in Hexane
Aroclor 1260 @1000 μg/mL in MeOH
Polychlorinated biphenyl (60% Cl)
Aroclor1260Solution,100mg/L,5x1ml
Aroclor 1260@1000 μg/mL in Hexane
Aroclor1260Solution,5,000mg/L,1ml
Aroclor1260Solution,1,000mg/L,1ml
Aroclor 1260@35 μg/mL in Isooctane
aroclor1260referencestandardforclp
Arochlor 1260 Solution in methanol
AROCLOR 1260, 1X1ML, ISO, 1000UG/ML
AROCLOR 1260, 1X1ML, MEOH, 200UG/ML
Aroclor1260Solution,1,000mg/L,5x1ml
AROCLOR 1260, 1X1ML, MEOH, 1000UG/ML
polychlorinatedbiphenyl(aroclor1260)
Aroclor 1260 @3.0 mg/mL in Isooctane
AROCLOR 1260, 1X1ML, HEXANE 1000UG/ML
Aroclor1260Solution,1,000mg/L,2x0.6ml
Aroclor1260inTransformerOil,2mg/L,1ml
Aroclor1260inTransformerOil,5mg/L,1ml
Aroclor1260inTransformerOil,2mg/Kg,5ml
Aroclor1260inTransformerOil,25mg/L,1ml
Aroclor1260inTransformerOil,10mg/L,1ml
Aroclor1260inTransformerOil,50mg/L,5ml
Aroclor1260inTransformerOil,50mg/L,1ml
Aroclor 1260 10 μg/g in Transformer Oil
Aroclor1260inTransformerOil,50mg/Kg,5ml
Aroclor1260inTransformerOil,50mg/L,25ml
Aroclor1260inTransformerOil,10mg/Kg,5ml
Aroclor1260inTransformerOil,500mg/L,5ml
Aroclor1260inTransformerOil,25mg/Kg,5ml
PCB Aroclor 1260 @500 μg/mL in Isooctane
Aroclor1260inTransformerOil,1000mg/L,5ml
Aroclor1260inTransformerOil,1000mg/L,25ml
PCB Aroclor 1260 @1000 μg/mL in Isooctane
Aroclor 1260 @50 ppm w/w in Transformer oil
Aroclor 1260@500 ppm w/w in Transformer oil
Aroclor1260SecondSourceSolution,200mg/L,1ml
L20126000CY Aroclor 1260 10μg/mLin Cyclohexan
X20126000CY Aroclor 1260 100μg/mLin Cyclohexa
Aroclor1260inTransformerOil,50mg/Kg(wt/wt),1ml
Aroclor 1260 Stock solution@5.0 mg/mL in MeOH
AROCLOR 1260, 1X5ML, TRANSFORMER OIL, 50 MG/KG
AROCLOR 1260, 1X5ML, TRANSFORMER OIL, 50 0MG/KG
articlescontainingpolychlorinatedbiphenyls(pcb)
ASTM Method D6160 Aroclor 1260 35 μg/mLin Isooctane
ASTM Method D4059 Aroclor 1260 500 μg/g in Transformer Oil
aroclor 1260, 60 perc.cl, pcb c12h5cl5 and c12h4cl6 and c12h2cl8
Polychlorinated biphenyl (Aroclor 1260): (Chlorodiphenyl (60% Cl))
[Molecular Formula]

PCB C12H5CI5 AND C12H4CI6 AND C12H2CI8
[MDL Number]

MFCD03001820
[MOL File]

11096-82-5.mol
[Molecular Weight]

60
Chemical PropertiesBack Directory
[Appearance]

Soft, sticky, light-yellow resin; approx- imately 6.3 chlorine atoms per molecule.
[Melting point ]

115.76°C (estimate)
[Boiling point ]

457.69°C (rough estimate)
[density ]

1.5800 (estimate)
[vapor pressure ]

130.5 at 25 °C (estimated using GC retention data, Foreman and Bidleman, 1985)
[refractive index ]

1.6270 (estimate)
[Fp ]

11 °C
[storage temp. ]

room temp
[solubility ]

Soluble in most solvents (U.S. EPA, 1985)
[Water Solubility ]

14.4ug/L(20 ºC)
[Henry's Law Constant]

0.244, 0.435, 0.754, 1.27, 2.10, 3.36, 5.27, 8.09, and 12.1 at 0.0, 5.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.5, and 40.0 °C, respectively (predicted, Burkhard et al., 1985)
[EPA Substance Registry System]

Aroclor 1260 (11096-82-5)
Safety DataBack Directory
[Hazard Codes ]

F,N,Xn,T
[Risk Statements ]

11-23/24/25-39/23/24/25-67-65-62-51/53-48/20-38-50/53-33-52/53-45
[Safety Statements ]

36/37-45-62-61-60-33-29-16-9-53
[RIDADR ]

2315
[WGK Germany ]

3
[HazardClass ]

9
[PackingGroup ]

II
[Safety Profile]

Confirmed carcinogen with carcinogenic and neoplastigenic data. Moderately toxic by ingestion and skin contact. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits highly toxic fumes of Cl-. Used in heat transfer, hydraulic fluids, lubricants, and insecticides. See also POLYCHLORINATED BIPHENYLS.
[Hazardous Substances Data]

11096-82-5(Hazardous Substances Data)
[Toxicity]

Suspected human carcinogen. Acute oral LD50 for rats 1,315 mg/kg (quoted, RTECS, 1985).
Hazard InformationBack Directory
[General Description]

Viscous oily liquid.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

Simple aromatic halogenated organic compounds are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: Toxic irritant. Hazardous decomposition products.
[Fire Hazard]

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
[Chemical Properties]

Soft, sticky, light-yellow resin; approx- imately 6.3 chlorine atoms per molecule.
[Physical properties]

Light yellow, sticky, soft, nonflammable resin with a faint odor
[Uses]

Secondary plasticizer for polyvinyl chloride; in polyester resins to increase strength of fiberglass; varnish formulations to improve water and alkali resistance; as an insulator fluid for electric condensers and as an additive in very high pressure lubricants. In fluorescent and highintensity discharge ballasts manufactured prior to 1979 (U.S. EPA, 1998).
Also used in wire or cable coatings; impregnants in cotton and asbestos braided insulation; coating on glass air filter pads, metal mesh to filter air and gas streams (Monsanto, 1960).
At a concentration of 5 to 25 wt %, increased the effective kill-life of the lindane spray up to 10 times. May have been used in chlordane and BHC insecticide formulations and in melt coatings for paper and cloth. In various nitrocellulose lacquers to impart weather resistance, luster, adhesion, and decreased burning rate. These lacquers may also contain dibutyl phthalate and/or tricresyl phosphate. A typical paper lacquer may contain acetone, isobutyl acetate, ethanol, toluene and up to 20 wt % PCB-1260 (Monsanto, 1960).
[Environmental Fate]

Biological. Reported degradation products by the microorganism Alcaligenes BM-2 for a mixture of polychlorinated biphenyls include monohydroxychlorobiphenyl, 2-hydroxy-6-oxochlorophenylhexa- 2,4-dieonic acid, chlorobenzoic acid, chlorobenzoylpropionic acid, chlorophenylacetic acid, and 3-chlorophenyl-2-chloropropenic acid (Yagi and Sudo, 1980). When PCB-1260 was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, no significant biodegradation was observed (Tabak et al., 1981).
Photolytic. PCB-1260 in a 90% acetonitrile/water solution containing 0.2 to 0.3 M sodium borohydride and irradiated with UV light (λ = 254 nm) reacted to yield dechlorinated biphenyls. After 2 h, about 75% of the congeners were destroyed. Without sodium borohydride, only 10% of the congeners had reacted. Products identified by GC include biphenyl, 2-, 3- and 4- chlorobiphenyl, six dichlorobiphenyls, three trichlorobiphenyls, 1-phenyl-1,4-cyclohexadiene, and 1-phenyl-3-cyclohexene (Epling et al., 1988).
Chemical/Physical. Zhang and Rusling (1993) evaluated the bicontinuous microemulsion of surfactant/oil/water as a medium for the dechlorination of polychlorinated biphenyls by electrochemical catalytic reduction. The microemulsion (20 mL) contained didodecyldimethylammonium bromide, dodecane, and water at 21, 57, and 22 wt %, respectively. The catalyst used was zinc phthalocyanine (4.5 nM). When PCB-1260 (100 mg), the emulsion and catalyst were subjected to a current of mA/cm2 on 11.2 cm2 lead electrode for 18 h, a dechlorination yield of >99.8 % was achieved. Reaction products included minor amounts of mono- and dichlorobiphenyls (0.02 mg), biphenyl and reduced alkylbenzene derivatives.
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