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ChemicalBook--->CAS DataBase List--->1037287-79-8

1037287-79-8

1037287-79-8 Structure

1037287-79-8 Structure
IdentificationBack Directory
[Name]

(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
[CAS]

1037287-79-8
[Synonyms]

CamphorNHC-Mes
(5aR,6S,9S,9aS)-2-Mesityl-6,11,11-trimethyl-5a,6,7,8,9,9a-hexahydro-4H-6,9-methanobenzo[b][1,2,4]triazolo[4,3-d][1,4]oxazin-2-ium Tetrafluoroborate,99%e.e.
(5aS,6R,9S,9aR)-5a,6,7,8,9,9a-Hexahydro-6,11,11-triMethyl-2-(2,4,6-triMethylphenyl)-6,9-Methano-4H-[1,2,4]triazolo[3,4-c][1,4]benzoxaziniuM tetrafluoroborate
[Molecular Formula]

C22H30BF4N3O
[MDL Number]

MFCD28144541
[MOL File]

1037287-79-8.mol
[Molecular Weight]

439.298
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

white to off-white
[Stability:]

hygroscopic
[CAS DataBase Reference]

1037287-79-8
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligand used in the diastereoselective and enantioselective desymmetrization of α-substituted cyclohexadienones via an intramolecular Stetter reaction.
  2. N-Heterocyclic, carbene-catalyzed, enantioselective intramolecular N-tethered aldehyde-ketone reactions.
  3. Desymmetrization of cyclohexadienones via intramolecular Stetter reaction to construct tricylic carbocycles.
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