Identification | Back Directory | [Name]
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate | [CAS]
1020085-61-3 | [Synonyms]
Piers-Grubbs 1st GRUBBS CATALYST C833 Grubbs Catalyst(TM) C833 Dichloro(PCy3)[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate dichloro(tricyclohexylphosphaniumylmethylidene)ruthenium:tricyclohexylphosphane:tetrafluoroborate Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranylidene)methyl]ruthenium tetrafluoroborate Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate 95% | [Molecular Formula]
C37H66BCl2F4P2Ru- | [MDL Number]
MFCD15144782 | [MOL File]
1020085-61-3.mol | [Molecular Weight]
832 |
Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
11 | [RIDADR ]
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all | [WGK Germany ]
1 |
Hazard Information | Back Directory | [Uses]
Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species. Has reactivity profile similar to Grubbs Catalyst? 1st Generation but is active at much lower temperatures (below 0 °C). | [Uses]
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species. It has reactivity profile similar to the Grubbs 1 st Generation Catalyst but is active at much lower temperatures (below 0 ℃). | [reaction suitability]
core: ruthenium reagent type: catalyst reaction type: Ring Opening Metathesis Polymerisation |
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