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ChemicalBook--->CAS DataBase List--->1020085-61-3

1020085-61-3

1020085-61-3 Structure

1020085-61-3 Structure
IdentificationBack Directory
[Name]

Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate
[CAS]

1020085-61-3
[Synonyms]

Piers-Grubbs 1st
GRUBBS CATALYST C833
Grubbs Catalyst(TM) C833
Dichloro(PCy3)[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate
dichloro(tricyclohexylphosphaniumylmethylidene)ruthenium:tricyclohexylphosphane:tetrafluoroborate
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranylidene)methyl]ruthenium tetrafluoroborate
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate
Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate 95%
[Molecular Formula]

C37H66BCl2F4P2Ru-
[MDL Number]

MFCD15144782
[MOL File]

1020085-61-3.mol
[Molecular Weight]

832
Chemical PropertiesBack Directory
[Melting point ]

203°C (dec.)
[storage temp. ]

2-8°C
[form ]

solid
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

11
[RIDADR ]

UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
[WGK Germany ]

1
Hazard InformationBack Directory
[Uses]

Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species. Has reactivity profile similar to Grubbs Catalyst? 1st Generation but is active at much lower temperatures (below 0 °C).
[Uses]

Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species. It has reactivity profile similar to the Grubbs 1 st Generation Catalyst but is active at much lower temperatures (below 0 ℃).
[reaction suitability]

core: ruthenium
reagent type: catalyst
reaction type: Ring Opening Metathesis Polymerisation
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